Nanoporous Gold


My small contribution to this field


Nanoporous gold is a freestanding material that can, for example, be obtained by electrochemically de-alloying a gold-silver alloy. Left is a porous structure which looks fascinating under the microscope and is made of ligaments and voids of several 10 nm in diameter. But not only that, it has a number of interesting properties, among those also a catalytic activity emerging from gold atoms with low coordination.
In the past 20 years there has been a plethora of studies on this material from groups around the globe. I got in contact with the material in the group of Prof. Marcus Bäumer in Bremen, Germany, who had a project on this material and was collaborating with Prof. Friend at Harvard on this topic. Arne Wittstock, who worked as a phd student on the topic, made some significant contributions to the field. (Find his thesis here (in German))
Marcus and Arne also co-edited a book on the topic in 2012.

I supported this project in 2009 with an initial XPS measurement on the material but later continued to study it in more detail as a postdoc in Uppsala together with Prof. Anders Sandell. During a few synchrotron beamtimes I studied the cleaning of np-Au with ozone treatment and also the addition of titanium dioxide to add further function to the material. Both studies were published (see below).
Back in Bremen I supported two studies that dealt with studying the CO oxidation capability in a model vacuum environment and a study that dealt with modifying np-Au with cerium oxide to use it wor the water-gas shift reaction.

In 2013 Marcus Bäumer and several groups in Germany successfully applied for a DFG "Forschergruppe", a collective national research effort working on the study and utilization of nanoporous gold. The Project was called "NAGOCAT" but unfortunately the project's website is no longer available. 

Publications




Nanoporous Gold-Supported Ceria for the Water–Gas Shift Reaction: UHV Inspired Design for Applied Catalysis


Junjie Shi, Andreas Schaefer, Andre Wichmann, M. Mangir Murshed, Thorsten M. Gesing, Arne Wittstock, Marcus Bäumer

The Journal of Physical Chemistry C, vol. 118, 2014, pp. 29270-29277




CO oxidation on nanoporous gold: A combined TPD and XPS study of active catalysts


Sarah Röhe, Kristian Frank, Andreas Schaefer, Arne Wittstock, Volkmar Zielasek, Andreas Rosenauer, Marcus Bäumer

Surface Science, vol. 609, 2013, pp. 106-112




Controlled modification of nanoporous gold: Chemical vapor deposition of TiO2 in ultrahigh vacuum


A. Schaefer, D. Ragazzon, L.E. Walle, M.H. Farstad, A. Wichmann, M. Bäumer, A. Borg, A. Sandell

Applied Surface Science, vol. 282, 2013, pp. 439-443




Toward Controlled Modification of Nanoporous Gold. A Detailed Surface Science Study on Cleaning and Oxidation


A. Schaefer, D. Ragazzon, A. Wittstock, L. E. Walle, A. Borg, M. Bäumer, A. Sandell

The Journal of Physical Chemistry C, vol. 116, 2012, pp. 4564-4571




Nanoporous Au: An Unsupported Pure Gold Catalyst?


Arne Wittstock, Björn Neumann, Andreas Schaefer, Karifala Dumbuya, Christian Kübel, Monika M. Biener, Volkmar Zielasek, Hans-Peter Steinrück, J. Michael Gottfried, Jürgen Biener, Alex Hamza, Marcus Bäumer

The Journal of Physical Chemistry C, vol. 113, 2009, pp. 5593-5600


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